This will be the first time that the Late Show has used the Ed Sullivan Theater as a concert venue. During the Webcast, the band will perform some of its classic songs as well as material from its self-titled new album, released Tuesday.
Pearl Jam's taped appearance on the Late Show will air later in the evening. The show begins at 11:35 p.m. ET/PT on CBS.
The is the band's eighth studio album and first in four years. At Tower Records in New York, thousands waited in line to buy the album at a midnight sale held early Tuesday morning. Some fans camped outside for as long as 48 hours at what reportedly was the biggest midnight sale in Tower's history.