Talia Balsam, seen here in 2007, was married to Clooney from 1989-1993. Clooney has said he didn't give the marriage a shot. He's never remarried.
Balsam is the daughter of actor Martin Balsam. She's married to Jon Slattery, who plays Roger Sterling on "Mad Men." She plays his ex-wife on the show.
George Clooney's exes: See who else the actor has dated