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Jessica Simpson + Gunthy-Renker = $7.5M

Jessica Simpson and other stars are paid a lots to talk about their bouts with acne and endorse the Proactiv acne treatment line. In 2005, Simpson signed a three-year deal with Gunthy-Renker at $2.5 million per year. Sean Combs and Alicia Keys both earned $3 million pitching Proactiv.

(Photo: AP Photo/Haraz N. Ghanbari)